Tricarbonylrhenium(I) and manganese(I) complexes of 2-(pyrazolyl)-4-toluidine
نویسندگان
چکیده
منابع مشابه
N-(2-Pyridyl)-4-toluidine
There are two mol-ecules in the asymmetric unit of the title compound, C(12)H(12)N(2), with dihedral angles between the aromatic rings of 48.35 (12) and 51.02 (12)°. In the crystal structure, both mol-ecules form inversion dimers, linked by pairs of N-H⋯N hydrogen bonds.
متن کاملN-(Quinoxalin-2-yl)-4-toluidine
The aromatic and the aromatic fused-rings in the title compound, C(15)H(13)N(3), open the angle at the planar N atom to 130.07 (13) and 129.98 (13)° in the two independent mol-ecules in the asymmetric unit. The amino N atom of one mol-ecule forms a hydrogen bond to the 4-N atom of an adjacent quinoxalinyl ring, generating a supra-molecular chain.
متن کاملN-(Pyrazin-2-yl)-4-toluidine
The two aromatic systems in the title compound, C(11)H(11)N(3), are inclined by 19.1 (1)°, whilst the angle at the central amino N atom is 130.3 (2)°. The amino group forms a hydrogen bond to the pyrazine N-4 atom of an adjacent mol-ecule, forming a chain motif.
متن کاملN-(4-Methyl-2-pyridyl)-p-toluidine
In the title compound, C(13)H(14)N(2), the dihedral angle between the aromatic rings is 48.1 (1)° and the bridging C-N-C bond angle is 127.24 (12)°. In the crystal, intermolecular N-H⋯N hydrogen bonding about a center of inversion generates a hydrogen-bonded dimer.
متن کاملPyrazolyl methyls prescribe the electronic properties of iron(II) tetra(pyrazolyl)lutidine chloride complexes.
A series of iron(II) chloride complexes of pentadentate ligands related to α,α,α',α'-tetra(pyrazolyl)-2,6-lutidine, pz(4)lut, has been prepared to evaluate whether pyrazolyl substitution has any systematic impact on the electronic properties of the complexes. For this purpose, the new tetrakis(3,4,5-trimethylpyrazolyl)lutidine ligand, pz**(4)lut, was prepared via a CoCl(2)-catalyzed rearrangeme...
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ژورنال
عنوان ژورنال: Journal of Organometallic Chemistry
سال: 2010
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2009.09.027